One-step synthesis, structure and methane dry reforming over ceria supported Ni-based catalysts

Reference Presenter Authors
06-080 Glageane da Silva Souza Souza, G.d.(Universidade Federal da Paraíba); Cesario, M.R.(Université du Littoral Côte d'Opale); Tidahy, L.(Université du Littoral Côte d'Opale); Gennequin, C.(Université du Littoral Côte d'Opale); Abi-aad, E.(Université du Littoral Côte d'Opale); Macedo, D.A.(Universidade Federal da Paraíba); Inocencio Silva, N.F.(Universidade Federal da Paraíba);
One-step synthesized Ni-based catalysts with Co/Cu additions and calcined in air at 700 °C had their catalytic activities towards dry reforming of methane (DRM) evaluated from 400 to 800 ºC. X-ray diffraction analysis confirmed the attainment of NiO, Co3O4, CuO, and Ce0.9Gd0.1O1.95 structures. The catalyst reducibility and its interaction with the gadolinium doped ceria support are influenced by the presence and amount of cobalt and copper. The NCo0.8 catalyst exhibited high CH4 and CO2 conversions, the best reaction selectivity and carbon resistance due to its high surface area and formation of the Ni-Co alloy which improves reducibility and metal-support interaction.
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